Photo-Induced Synthesis of Ytterbium and Manganese-Doped CsPbCl₃ Nanocrystals for Visible to Near-Infrared Photoluminescence with Negative Thermal Quenching

Authors：Xiaochen Fang+, Zhuo Chen+, Liwei Wang*, Biao Zheng*, Meng An*, Yusuke Yamauchi* and Zhanhui Yuan*

Abstract：Rare-earth-doped all-inorganic perovskite applications for near-infrared (NIR) emission are crucial for the construction of the next generation of intelligent lighting sources. However, the preparation of rare-earth-doped all-inorganic perovskite is complex, and difficult to control, and the issue of thermal quenching poses significant challenges to its practical application. Here, in order to address these issues, a convenient photo-induced synthesis method for CsPbCl3:Mn/Yb nanocrystals (NCs) is proposed by decomposing carbon tetrachloride with 365 nm light to provide chloride ions and regulate the formation of perovskite at room temperature. The negative thermal quenching in the NIR emission is achieved through the energy transfer between Mn and Yb. The emission intensity of Yb enhances 3.2 times when the temperature rises to ≈427 K. Furthermore, with the help of the orange emission from the Mn2+ ions and the NIR emission from the Yb3+ ions, visible to NIR light emitting diode (LED) devices are constructed and applied in orange light illumination and night vision imaging. This study enriches the preparation methods and chemical research on perovskite doping, which may open up new opportunities for the widespread application of perovskite-based materials or device engineering.

DOI:https://doi.org/10.1002/advs.202408927